Category: 17524-05-9

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Chemistry – An Asian Journal called Molybdenum Carbide-Embedded Multichannel Hollow Carbon Nanofibers as Bifunctional Catalysts for Water Splitting, Author is Ji, Changchun; Yang, Guang; Ilango, P. Robert; Song, Junnan; Yu, Deshuang; Han, Sujun; Zhang, Dongxing; Li, Linlin; Peng, Shengjie, which mentions a compound: 17524-05-9, SMILESS is O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O, Molecular C10H14MoO6, Computed Properties of C10H14MoO6.

With the environmental pollution and non-renewable fossil fuels, it is imperative to develop eco-friendly, renewable, and highly efficient electrocatalysts for sustainable energy. Herein, a simple electrospinning process used to synthesis Mo2C-embedded multichannel hollow carbon nanofibers (Mo2C-MCNFs) and followed by the pyrolysis process. As prepared lotus root-like nanoarchitecture could offer rich porosity and facilitate the electrolyte infiltration, the Mo2C-MCNFs delivered favorable catalytic activity for HER and OER. The resultant catalysts exhibit low overpotentials of 114 mV and 320 mV at a c.d. of 10 mA cm-2 for HER and OER, resp. Furthermore, using the Mo2C-MCNFs catalysts as a bifunctional electrode toward overall water splitting, which only needs a small cell voltage of 1.68 V to afford a c.d. of 10 mA cm-2 in the home-made alk. electrolyzer. This interesting work presents a simple and effective strategy to further fabricating tunable nanostructures for energy-related applications.

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Asha, T. M.; Sithambaresan, M.; Prathapachandra Kurup, M. R. published an article about the compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9,SMILESS:O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O ).Electric Literature of C10H14MoO6. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:17524-05-9) through the article.

Four new mononuclear dioxidomolybdenum(VI) complexes [MoO2LD] (D = methanol (1), ethanol (2), propanol (3) and [MoO2LD]2·D (D = 4-picoline (4))) were synthesized by the reaction of [MoO2(acac)2] with the thiosemicarbazone (H2L) derived from 3-ethoxy-2-hydroxybenzaldehyde and N4-(3-methoxyphenyl)thiosemicarbazone in presence of donor solvents like methanol, ethanol, propanol and 4-picoline. Crystal and mol. structures of the complexes were determined by single crystal x-ray diffraction anal. All the complexes portrayed similar mononuclear structures where the thiosemicarbazone is bonded to molybdenum(VI) ion as a bineg. tridendate agent. The molybdenum(VI) center in complexes 1-4 is six coordinate by the thiosemicarbazone, two oxido groups and an oxygen or nitrogen atom from the donor solvent mols. The complexes 1-4 exhibit oxygen atom transfer to PPh3 in acetonitrile medium in presence of N-N bidendate donors to form [Mo(IV)OL(N-N)] (N-N = 2-2′ bipyridine (5) or 1,10 phenanthroline (6)). The complexes were further characterized by elemental anal., spectroscopic methods (IR, UV-visible and 1H NMR) and TGA. The electrochem. behavior of these complexes were investigated for an insight into the redox behavior of the molybdenum(VI) centers in these complexes. Hirshfeld surface anal. was successfully employed for exploring the coordination geometries and various noncovalent interactions present in their crystal structures. Also, the catalytic abilities of 1-4 were tested for the oxidation of styrene using aqueous H2O2 as oxidant and NaHCO3 as co-catalyst. The reaction condition for all-out catalytic proficiency of the catalysts 1-4 were examined by studying the effect of various parameters such as the amount of catalyst, H2O2, co-catalyst (NaHCO3) and solvent (CH3CN) as well as temperature of the reaction. Almost 97-98% product selectivity was attained for the oxidation of styrene to styrene oxide.

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Related Products of 17524-05-9. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Stable Bimetallene Hydride Boosts Anodic CO Tolerance of Fuel Cells. Author is Wu, Jiandong; Cui, Xiaoqiang; Fan, Jinchang; Zhao, Jingxiang; Zhang, Qinghua; Jia, Guangri; Wu, Qiong; Zhang, Dantong; Hou, Changmin; Xu, Shan; Jiao, Dongxu; Gu, Lin; Singh, David J.; Zheng, Weitao.

Active and durable anode electrocatalysts are of vital importance for practical implementation of fuel cells. However, the surface-adsorbed reaction intermediates, especially CO, easily poison and deactivate the electrocatalysts. Here, we report ultrathin molybdenum-palladium hydride (MoPdH) bimetallene as a high-efficiency electrocatalyst for the methanol oxidation reaction. This exhibits a 6.0-fold enhancement of mass activity relative to com. Pd black catalyst. Alloying with Mo strongly enhances the H binding ability of Pd and thereby stabilizes the MoPdH bimetallene. The resulting ultrathin hydride structure and the stabilization of it by Mo alloying yields a MoPdH bimetallene with the outstanding CO tolerance. The stabilization is understood in terms of the Miedema rule, which thus provides a new opportunity for catalyst design boosting the commercialization of fuel cells based on stable bimetallene hydride nanosheets.

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