Category: 4556-23-4

Li, Kan; Li, Jing-jing; Zhao, Ni; Xie, Ting-ting; Di, Bin; Xu, Li-li published the article 《Thioether-based recyclable metal-organic frameworks for selective and efficient removal of Hg2+ from water》. Keywords: thioether metal organic framework removal mercury.They researched the compound: Pyridine-4-thiol( cas:4556-23-4 ).Safety of Pyridine-4-thiol. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:4556-23-4) here.

Hg2+ is highly toxic and hazardous and widely found in polluted water. To remove mercury ions from wastewater, there is an urgent need to investigate and develop new adsorbents. Herein, we synthesized three novel thioether-based metal-organic frameworks (MOFs) through a facile diffusion method or a solvothermal strategy, i.e. [(ZnCl2)3(L1)2·χ(solvent)]n (1), [(Cu2I3O2)4(CH4N0.5)4(L1)4(DMA)4·3(H2O)·χ(solvent)]n (2) and [(CuBr2)2(L2)2 CH3CN·χ(solvent)]n (3), where L1 = 1,3,5-tris((pyridin-4-ylthio)methyl)benzene and L2 = 2,4,6-trimethoxy-1,3,5-tris((pyridin-4-ylthio)methyl)benzene. The obtained thioether-based MOFs were characterized by single-crystal X-ray diffraction, Fourier transform IR spectroscopy, elemental anal. and thermogravimetric anal. Further studies revealed that they could remove Hg2+ from water. They have high adsorptivity (up to 362 mg g-1) and are highly efficient in removing Hg2+ (up to 95%). Besides, these MOFs can be recycled and can selectively remove Hg2+ from water in the presence of other metal ions. Consequently, these MOFs are highly promising candidates for the selective absorption and removal of mercury ions from water.

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Zhang, Meng; Wang, Yanan; Wang, Xu; Zhao, Bing; Ruan, Weidong published the article 《Surface-enhanced Raman scattering (SERS) on indium-doped CdO (ICO) substrates: New charge-transfer enhancement contribution from electrons in conduction bands》. Keywords: surface enhanced Raman scattering indium doped cadmium oxide; charge transfer enhancement contribution electron conduction band.They researched the compound: Pyridine-4-thiol( cas:4556-23-4 ).Name: Pyridine-4-thiol. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:4556-23-4) here.

Surface-enhanced Raman scattering (SERS) substrates have shown rapid development in recent years, but the use of transparent conductive oxides (TCOs) in SERS is still limited. Here, a series of In-doped CdO (ICO) NPs with different In3+ doping contents x (x = 0, 0.025, 0.050, 0.075, 0.100, 0.125, 0.150, and 0.200) were synthesized by a hydrothermal method and first employed as a SERS platform. The structures and properties of the ICO NPs influenced by dopant concentration of In3+ ions were characterized by powder X-ray diffraction (XRD), inductively coupled plasma (ICP) anal., SEM (SEM), XPS, and Fourier transform IR (FTIR) spectroscopy. Furthermore, the SERS spectra of ICO-MPY were investigated. Interestingly, the enhancement was dominated by the charge-transfer (CT) contribution through the free electrons in conduction bands (CBs). The changes in electronic distributions in energy levels of ICO NPs at different doping contents were explored, and the corresponding effect on SERS was discussed by employing 633 and 785 nm excitation lines, resp. The CT route was found to be the excitation of electrons from CBs of semiconductor to the LUMO of mol., which provides a new perspective in understanding SERS mechanisms. The present work provides a new approach to develop potential semiconductive SERS substrates.

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Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Pyridine-4-thiol, is researched, Molecular C5H5NS, CAS is 4556-23-4, about Eliminating irreproducibility in SERS substrates.Formula: C5H5NS.

Irreproducibility in surface-enhanced Raman spectroscopy (SERS) due to variability among substrates is a source of recurrent debate within the field. It is regarded as a major hurdle towards the widespread adoption of SERS as a sensing platform. Most of the literature focused on developing substrates for various applications considers reproducibility of lower importance. Here, we address and analyze the sources of this irreproducibility in order to show how these can be minimised. We apply our findings to a simple substrate demonstrating reproducible SERS measurements with relative standard deviations well below 1% between different batches and days. Identifying the sources of irreproducibility and understanding how to reduce these can aid in the transition of SERS from the lab to real-world applications.

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In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called SERS active substrates of gold nanoparticles embedded in the pool of 5-CB liquid crystal molecules organized in Langmuir-Reverse Schaefer films: A facile fabrication route to make the topological defects useful, published in 2019-08-01, which mentions a compound: 4556-23-4, mainly applied to gold cyano pentylbiphenyl Langmuir Reverse Schaefer film topol defect, HPLC of Formula: 4556-23-4.

This paper reports for the first time, fabrications of SERS active substrates I and II from Langmuir Reverse Schaefer (L-R Sh) films of 5-CB nematic liquid crystal mols. immersed in gold nanocolloids for 36 and 48 h resp. Under parallel or slightly crossed polarizations, the POM images of these two substrates exhibit micro aggregated textures embedded in the pool of 5-CB mols. Under crossed polarizations, the aggregated textures disappear with the appearance of bright birefringent defects of various sizes and shapes. The rationale behind the evolution of such micro aggregated textures and spatial locations of birefringent defects in these substrates are suggested. The FESEM images of the substrates exhibit distinctive patterns driven by the birefringent defects and confirm trapping of gold nanoparticles within the defect sites. The instabilities appeared in the patterns are estimated from statistical considerations in terms of Hurst exponent and phase space trajectories. The chaotic domains prevailing in these substrates are confirmed from the Lyapunov exponents. The efficacies of both the substrates as efficient SERS sensing platform have been tested to detect 4-MPy mols. at trace concentration The as prepared substrates can be used as “”lab on a chip”” for chem. and biochem. sensing at ultralow concentrations

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Ding, Xin; Tuikka, Matti; Haukka, Matti published an article about the compound: Pyridine-4-thiol( cas:4556-23-4,SMILESS:SC1=CC=NC=C1 ).SDS of cas: 4556-23-4. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:4556-23-4) through the article.

Sulfur is a widely used halogen bond (XB) acceptor, but only a limited number of neutral XB acceptors with bifurcated sp3-S sites have been reported. In this work, a new bidentate XB acceptor, 1-(4-pyridyl)-4-thiopyridine (PTP), which combines sp3-S and sp2-N acceptor sites, is introduced. Three halogen bonded cocrystals were obtained by using 1,4-diiodobenzene (DIB), 1,4-diiodotetrafluorobenzene (DIFB), and iodopentafluorobenzene (IPFB) as XB donors and PTP as acceptor. The structures of the cocrystals showed some XB selectivity between the S and N donors in PTP. However, the limited contribution of XB to the overall mol. packing in these three cocrystals and the results from DSC measurements clearly point out the synergetic influence and interplay of all noncovalent interactions in crystal packing of these compounds

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SDS of cas: 4556-23-4. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Pyridine-4-thiol, is researched, Molecular C5H5NS, CAS is 4556-23-4, about Tuning the electrochemical behavior of organodisulfides in rechargeable lithium batteries using N-containing heterocycles. Author is Wang, Dan-Yang; Si, Yubing; Li, Junjie; Fu, Yongzhu.

S-S bonds in organodisulfides can break and obtain Li+ and e- in the discharge of lithium batteries. Organodisulfides provide precise lithiation sites, and therefore are valuable models for the study of redox reactions in lithium batteries. To understand their electrochem. behavior, we investigate three disulfides with different N-containing heterocycles including 2,2′-dipyridyl disulfide (2,2′-DpyDS), 4,4′-dipyridyl disulfide (4,4′-DpyDS), and 2,2′-dipyridyl disulfide-N,N’-dioxide (DpyDSDO). The three disulfides all show higher discharge voltage plateaus due to the electron-withdrawing groups: DPDS (2.20 V) < 2,2'-DpyDS (2.45 V) = 4,4'-DpyDS (2.45 V) < DpyDSDO (2.80 V). In particular, 2,2'-DpyDS exhibits an outstanding 69% capacity retention over 500 cycles. Our theor. simulations show that lithium pyridine-2-thiolate, the discharge product of 2,2'-DpyDS, forms compact clusters via N···Li···S bridges coordinated by lithium ions, which can help reduce its dissolution in liquid electrolyte, and therefore increase the cycle life. Liquid chromatog.-mass spectrometry is demonstrated to be a powerful tool for the investigation of discharge/recharge products of soluble organodisulfides in rechargeable lithium batteries. In some applications, this compound(4556-23-4)SDS of cas: 4556-23-4 is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.

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Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Chemical Science called Effect of nanostructuration on the spin crossover transition in crystalline ultrathin films, Author is Rubio-Gimenez, Victor; Bartual-Murgui, Carlos; Galbiati, Marta; Nunez-Lopez, Alejandro; Castells-Gil, Javier; Quinard, Benoit; Seneor, Pierre; Otero, Edwige; Ohresser, Philippe; Cantarero, Andres; Coronado, Eugenio; Real, Jose Antonio; Mattana, Richard; Tatay, Sergio; Marti-Gastaldo, Carlos, which mentions a compound: 4556-23-4, SMILESS is SC1=CC=NC=C1, Molecular C5H5NS, Computed Properties of C5H5NS.

Mastering the nanostructuration of mol. materials onto solid surfaces and understanding how this process affects their properties are of utmost importance for their integration into solid-state electronic devices. This is even more important for spin crossover (SCO) systems, in which the spin transition is extremely sensitive to size reduction effects. These bi-stable materials have great potential for the development of nanotechnol. applications provided their intrinsic properties can be successfully implemented in nanometric films, amenable to the fabrication of functional nanodevices. Here we report the fabrication of crystalline ultrathin films (<1-43 nm) of two-dimensional Hofmann-type coordination polymers by using an improved layer-by-layer strategy and a close examination of their SCO properties at the nanoscale. X-ray absorption spectroscopy data in combination with extensive at. force microscopy anal. reveal critical dependence of the SCO transition on the number of layers and the microstructure of the films. This originates from the formation of segregated nanocrystals in early stages of the growth process that coalesce into a continuous film with an increasing number of growth cycles for an overall behavior reminiscent of the bulk. As a result, the completeness of the high spin/low spin transition is dramatically hindered for films of less than 15 layers revealing serious limitations to the ultimate thickness that might be representative of the performance of the bulk when processing SCO materials as ultrathin films. This unprecedented exploration of the particularities of the growth of SCO thin films at the nanoscale should encourage researchers to put a spotlight on these issues when contemplating their integration into devices. In some applications, this compound(4556-23-4)Computed Properties of C5H5NS is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.

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Safety of Pyridine-4-thiol. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Pyridine-4-thiol, is researched, Molecular C5H5NS, CAS is 4556-23-4, about Overcurrent Electrodeposition of Fractal Plasmonic Black Gold with Broad-Band Absorption Properties for Excitation-Immune SERS. Author is Yu, Renpeng; Wang, Jingyu; Han, Mei; Zhang, Mengyao; Zeng, Pei; Dang, Weiqi; Liu, Jianfang; Yang, Zhilin; Hu, Jiawen; Tian, Zhongqun.

The dependence of plasmon resonance on the size, shape, and interparticle spacing of single, isolated nanostructures inherently limits their light-harvesting capability to a narrow spectral band. Here, we report a facile overcurrent electrodeposition strategy to prepare fractal plasmonic black gold (B-Au) with broad-band absorption properties (over 80% throughout the range of 300-1800 nm). The broad-band absorption properties are attributed to the excitation of multiple plasmons in the B-Au, which results in strong light-matter interaction over a broad-band spectral window. Consequently, the B-Au can produce strong broad-band surface-enhanced Raman scattering (SERS) regardless of the excitation light used. These findings demonstrate that the fractal B-Au allows efficient utilization of broad spectral photons and opens up exciting opportunities for highly sensitive SERS detection, photocatalysis, and photovoltaic devices.

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Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 4556-23-4, is researched, Molecular C5H5NS, about Evaluation of the intrinsic pH sensing performance of surface-enhanced Raman scattering pH probes, the main research direction is hydrogen ion sensing surface enhanced Raman scattering probe.Computed Properties of C5H5NS.

Surface-enhanced Raman spectroscopy (SERS) has shown a high promise in microenvironmental pH sensing in recent years, which is significant for understanding various biol. processes and multiphase chem. reactions. Generally, the pH sensing capability of the SERS substrate is realized by the surface functionalization of the substrate with a pH sensitive mol. (pH probe). However, to the best of our knowledge, there is no systematic evaluation of mainstream SERS pH probes reported in literatures on the pH response range, resistance to co-present ions, accuracy and stability. Here a systematic anal. of common pH probes, including 4-mercaptobenzoic acid (4-MBA), 4-mercaptopyridine (4-Mpy), 2-aminobenzenethiol (2-ABT), and 4-aminothiophenol (4-ATP) has been carried out with a series of performance assessments. D. functional theory (DFT) calculation was carried out to investigate the vibration mode in SERS spectra. Moreover, the practical application comparison was conducted with urine samples. Overall, 4-MBA showed an excellent sensing performance in the neutral and alk. area, and meanwhile, the pH response of 4-Mpy and 4-ATP was inclined to the acidic and neutral range. The pH probe 2-ABT is not recommend because of the poor performance.

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Recommanded Product: Pyridine-4-thiol. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Pyridine-4-thiol, is researched, Molecular C5H5NS, CAS is 4556-23-4, about MoS2/graphene van der Waals heterojunctions combined with two-layered Au NP for SERS and catalysis analyse. Author is Lu, Weixi; Liu, Lu; Zhu, Tiying; Li, Zhaoxiang; Shao, Mingrui; Zhang, Chao; Yu, Jing; Zhao, Xiaofei; Yang, Cheng; Li, Zhen.

MoS2-plasmonic hybrid platforms have attracted significant interest in surfaceenhanced Raman scattering (SERS) and plasmon-driven photocatalysis. However, direct contact between the metal and MoS2 creates strain that deteriorates the electron transport across the metal/ MoS2 interfaces, which would affect the SERS effect and the catalytic performance. Here, the MoS2/graphene van der Waals heterojunctions (vdWHs) were fabricated and combined with two-layered gold nanoparticles (Au NP) for SERS and plasmon-driven photocatalysis analyze. The graphene film is introduced to provide an effective buffer layer between Au NP and MoS2, which not only eliminates the inhomogeneous contact on MoS2 but also benefits the electron transfer. The substrate exhibits excellent SERS capability realizing ultra-sensitive detection for 4-pyridinethiol mols. Also, the surface catalytic reaction of p-nitrothiophenol (PNTP) to p,p-dimercaptobenzene (DMAB) conversion was in situ monitored, demonstrating that the vdWHs-plasmonic hybrid could effectively accelerate reaction process. The mechanism of the SERS and catalytic behaviors are investigated via experiments combined with theor. simulations (finite element method and quantum chem. calculations).

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