Category: 95-11-4

Recently I am researching about TRANSFUSION PREDICTION; PRIMARY SURGERY; IMPACT; RADIOTHERAPY; HEMOGLOBIN, Saw an article supported by the . Recommanded Product: 5-Norbornene-2-carbonitrile. Published in CHURCHILL LIVINGSTONE in EDINBURGH ,Authors: Rogers, SN; Horisk, K; Groom, P; Lowe, D. The CAS is 95-11-4. Through research, I have a further understanding and discovery of 5-Norbornene-2-carbonitrile

Our main aims were to assess haemoglobin (Hb) concentrations from preoperative assessment to discharge from hospital, and to review which patients had blood transfusions and compliance with national transfusion guidelines. We studied a consecutive series of 131 patients between October 2016 and September 2017 who had either neck dissection or resection and free microvascular tissue transfer. Half the patients had soft tissue free flaps (n=65), 26% had composite free flaps (n = 34), and 24% neck dissection only (n =32). Using the WHO definition of anaemia, 4% (1/28) of patients who had neck dissections and 19% (16/85) of those who had free flaps were anaemic preoperatively. The median (IQR) Hb at discharge was 131 (119-144) g/L for patients who had neck dissections, 103 (95-114) g/L for those who had soft free flaps, and 95 (90-104) g/L for those who had composite free flaps. No patients who had neck dissection were given a red blood cell (RBC) transfusion, whereas they were given to 26/99 (26%) of those who had free flaps. Hb concentrations were checked after each unit in 31/39 transfusions (79%). Concentrations for those who had free flaps fell by about 30 g/L from admission to operation, and only four patients were given tranexamic acid peroperatively. Postoperatively Hb remained at similar concentrations until discharge, with 23/98 (24%) given iron orally on discharge. In terms of compliance with blood transfusion guidelines there was a notable absence of the use of tranexamic acid and of iron intravenously. An increase in their use could potentially reduce the number of blood transfusions required and the postoperative incidence of anaemia, and have a favourable effect on outcomes such as complications, fatigue, and overall quality of life. (C) 2019 The British Association of Oral and Maxillofacial Surgeons. Published by Elsevier Ltd. All rights reserved.

About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Rogers, SN; Horisk, K; Groom, P; Lowe, D or concate me.. Recommanded Product: 5-Norbornene-2-carbonitrile

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
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An article Modular Dual-Tasked C-H Methylation via the Catellani Strategy WOS:000490358900033 published article about PALLADIUM-CATALYZED ALKYLATION; LATE-STAGE FUNCTIONALIZATION; AROMATIC FUNCTIONALIZATION; SELECTIVE ALKYLATION; COUPLING REACTIONS; ARYL IODIDES; REAGENTS; BONDS; ACTIVATION; NORBORNENE in [Gao, Qianwen; Shang, Yong; Song, Fuzhen; Ye, Jinxiang; Liu, Ze-Shui; Li, Lisha; Cheng, Hong-Gang; Zhou, Qianghui] Wuhan Univ, Engn Res Ctr Organosilicon Cpds & Mat, Sauvage Ctr Mol Sci, Coll Chem & Mol Sci,Minist Educ, Wuhan 430072, Peoples R China; [Zhou, Qianghui] Wuhan Univ, Inst Adv Studies, Wuhan 430072, Peoples R China in 2019, Cited 91. The Name is 5-Norbornene-2-carbonitrile. Through research, I have a further understanding and discovery of 95-11-4. Product Details of 95-11-4

We report a dual-tasked methylation that is based on cooperative palladium/norbornene catalysis. Readily available (hetero)aryl halides (39 iodides and 4 bromides) and inexpensive MeOTs or trimethylphosphate are utilized as the substrates and methylating reagent, respectively. Six types of ipso terminations can modularly couple with this ortho C-H methylation to constitute a versatile methylation toolbox for preparing diversified methylated arenes. This toolbox features inexpensive methyl sources, excellent functional-group tolerance, simple reaction procedures, and scalability. Importantly, it can be uneventfully extended to isotope-labeled methylation by switching to the corresponding reagents CD3OTs or (CH3OTs)-C-13. Moreover, this toolbox can be applied to late-stage modification of biorelevant substrates with complete stereoretention. We believe these salient and practical features of our dual-tasked methylation toolbox will be welcomed by academic and industrial researchers.

Product Details of 95-11-4. About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Gao, QW; Shang, Y; Song, FZ; Ye, JX; Liu, ZS; Li, LS; Cheng, HG; Zhou, QH or concate me.

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
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Name: 5-Norbornene-2-carbonitrile. In 2021 MED ORAL PATOL ORAL published article about VERTICAL DISTRACTION; COMPLICATIONS; AUGMENTATION; IMPLANTS; DEVICES in [Manuel Somoza-Martin, Jose; Vazquez-Casal, Alba] Univ Santiago de Compostela, Fac Dent, Oral Med & Surg Unit, Entrerrios S-N, Santiago De Compostela 15782, Spain; [Suarez-Cunqueiro, Mercedes] Univ Santiago de Compostela, Fac Dent, Integrated Adult Clin Dent, Santiago De Compostela, Spain; [Garcia-Garcia, Abel; Gandara-Vila, Pilar; Perez-Sayans, Mario] Univ Santiago de Compostela, Fac Dent, Oral Surg & Implantol Unit, Oral Med, Santiago De Compostela, Spain; [Garcia-Garcia, Abel; Gandara-Vila, Pilar; Perez-Sayans, Mario] Inst Invest Sanitaria Santiago IDIS, Santiago De Compostela, Spain in 2021, Cited 28. The Name is 5-Norbornene-2-carbonitrile. Through research, I have a further understanding and discovery of 95-11-4.

Background: To perform a morphologic classification based on the results of bone augmentation after a distraction osteogenesis. Material and Methods: Thirty-four (34) patients (24 women and 10 men; mean age, 47.1 years (SD=9.5); age range, 23 to 62 years) underwent a total of 42 alveolar ridge distractions before the placement of a total of 89 dental implants. Ridge bone morphology was evaluated as the main ordinal variable. Chi-squared, Kruskal-Wallis and ANOVA one-way test were used. Results: Category I (30.95%): consisted of wide alveolar rim and no bone defects Category II (28.57%): wide alveolar rim, lateral bone surface concavity. Category III (23.81%): narrow alveolar rim, lateral bone surface concavity. Category IV (2.38%): distraction transport segment forming a bridge, without bone formed beneath and requiring guided bone regeneration. Category V (9.52%): return of the transport segment to its initial position due to the reverse rotation of the distractor screw. Category VI (4.76%): distraction transport segment completely lost. Subcategory D (28.57%), consisted of lingual deviation of the distraction axis, occurring in any of the categories I to IV. More men (76.9%) presented with category I (p<0.001). The use of the chisel resulted mainly in categories I and II (69.4%) (p<0.001). GBR was only required in 23.1% of the cases in Category I (p=0.011). The bone height achieved decreases as the category increases, due to the accompanying osteogenic limitations (p<0.001). The implants placed in category I were longer 11.5 +/- 0.9 mm (CI95% 10.9-11.9 mm) compared to those placed in category III with a length of 10.4 +/- 1.5 mm (CI95% 9.5-11.4 mm) (p=0.035). Conclusions: The alveolar ridge after distraction osteogenesis could be divided into six morphologic categories which provide a useful basis for decision-making regarding implant placement. Name: 5-Norbornene-2-carbonitrile. About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Somoza-Martin, JM; Vazquez-Casal, A; Suarez-Cunqueiro, M; Garcia-Garcia, A; Gandara-Vila, P; Perez-Sayans, M or concate me.

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
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Farra, SL; Gneuhs, M; Hodgson, E; Kawosa, B; Miller, ET; Simon, A; Timm, N; Hausfeld, J in [Farra, Sharon L.] Wright State Univ, Coll Nursing & Hlth, 3640 Colonel Glenn Hwy, Dayton, OH 45435 USA; [Gneuhs, Matthew] Cincinnati Childrens Hosp & Med Ctr, Emergency Preparedness & Response, Cincinnati, OH USA; [Hodgson, Eric] Miami Univ, Smale Interact Visualizat Ctr, Coral Gables, FL USA; [Kawosa, Burhan] Wright State Univ, Raj Soin Coll Business, Dayton, OH 45435 USA; [Miller, Elaine T.] Univ Cincinnati, Coll Nursing, Cincinnati, OH 45221 USA; [Simon, Ashley] Cincinnati Childrens Hosp Med Ctr, Neonatal Intens Care Unit, Cincinnati, OH 45229 USA; [Timm, Nathan] Univ Cincinnati, Coll Med, Cincinnati, OH 45221 USA; [Timm, Nathan] Cincinnati Childrens Hosp Med Ctr, Div Emergency Med, Cincinnati, OH 45229 USA; [Hausfeld, Jackie] Cincinnati Childrens Hosp & Med Ctr, Patient Serv Inst, Cincinnati, OH USA published Comparative Cost of Virtual Reality Training and Live Exercises for Training Hospital Workers for Evacuation in 2019, Cited 22. COA of Formula: C8H9N. The Name is 5-Norbornene-2-carbonitrile. Through research, I have a further understanding and discovery of 95-11-4.

Adoption of virtual reality technology may be delayed due to high up-front costs with unknown returns on that investment. In this article, we present a cost analysis of using virtual reality as a training tool. Virtual reality was used to train neonatal intensive care workers in hospital evacuation. A live disaster exercise with mannequins was also conducted that approximated the virtual experience. Comparative costs are presented for the planning, development, and implementation of both interventions. Initially, virtual reality is more expensive, with a cost of $229.79 per participant (total cost $18 617.54 per exercise) for the live drill versus $327.78 (total cost $106 951.14) for virtual reality. When development costs are extrapolated to repeated training over 3 years, however, the virtual exercise becomes less expensive with a cost of $115.43 per participant, while the cost of live exercises remains fixed. The larger initial investment in virtual reality can be spread across a large number of trainees and a longer time period with little additional cost, while each live drill requires additional costs that scale with the number of participants.

COA of Formula: C8H9N. About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Farra, SL; Gneuhs, M; Hodgson, E; Kawosa, B; Miller, ET; Simon, A; Timm, N; Hausfeld, J or concate me.

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
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Computed Properties of C8H9N. Alnaimat, AS; Barciela-Alonso, MC; Herbello-Hermelo, P; Dominguez-Gonzalez, R; Bermejo-Barrera, P in [Alnaimat, Ala S.; Carmen Barciela-Alonso, Maria; Herbello-Hermelo, Paloma; Dominguez-Gonzalez, Raquel; Bermejo-Barrera, Pilar] Univ Santiago de Compostela, Dept Analyt Chem Nutr & Bromatol, Fac Chem, Grp Trace Elements Speciat & Spect GETEE,Strateg, Ave Ciencias S-N, Santiago De Compostela 15782, Spain; [Alnaimat, Ala S.] Al Hussein Bin Talal Univ, Coll Sci, Dept Chem, Maan, Jordan published In vitro assessment of major and trace element bioaccessibility in tea samples in 2021, Cited 46. The Name is 5-Norbornene-2-carbonitrile. Through research, I have a further understanding and discovery of 95-11-4.

Bioaccessibility of trace elements (Li, Be, Ti, Ga, Cu, Ag, Hg, Cd, Cs, Pt, Tl, Pb, As, Cr, Co, Ni, V, Se, Sn and Sb) and major elements (Rb, Ba, Al, Fe, Zn, Si, Ca, Mg, Mn, Mo, Sr, P and K) in tea infusions has been assessed using an in vitro dialyzability protocol. Gastric simulation (using pepsin solution) and intestinal simulation (using pancreatin and bile salts) were used to perform the in vitro digestion. ICP-MS, ICP-OES and FAES were used for elements determination in digested tea leaves, their infusions and the dialyzate fractions from tea infusions. Microwaves assisted acid digestion was used for the total element determination in tea leaves, while tea infusions were prepared by brewing tea leaves for 5 min in boiling water. The LODs for elements determined in tea leaves were in the range of 0.11-656 ng g(-1) and 0.02-145.6 mu g g(-1) for trace and major elements, respectively. For elements’ determination in tea infusions, the LODs were ranged between 0.23 and 399.9 ng L-1 for trace elements and 0.2-1248 mu g L-1 for major elements. The LODs for the elements in the dialyzable fraction varied from 0.018 to 142 mu g L-1. The accuracy of the total element determination was evaluated using certified reference materials (Tea Leaves INCT-TL-1 and Rye Grass). The analytical recoveries were also assessed for analyzed elements in digested tea leaves (95-114%) and their infusions (92-115%), showing good recoveries. Among the studied elements, K was the most abundant element in tea leaves and tea infusions in almost all samples, followed by Ca, Mg, and P. Zn, Cs, and K showed the highest dialyzability percentages up to 84%, 76%, and 54%, respectively, followed by Si and Ca and K that show moderate to high dialyzability percentages. The accuracy of the dialysis process was evaluated using a mass-balance study.

About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Alnaimat, AS; Barciela-Alonso, MC; Herbello-Hermelo, P; Dominguez-Gonzalez, R; Bermejo-Barrera, P or concate me.. Computed Properties of C8H9N

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
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An article Muscle strength and body fat percentage in children and adolescents from the Maule region, Chile WOS:000576374100007 published article about HANDGRIP STRENGTH; PHYSICAL-ACTIVITY; FITNESS; GRIP; MATURITY; OBESITY; WEIGHT; VALUES; MASS in [Cossio-Bolanos, Marco] Univ Catolica Maule, Dept Sci Phys Act, Talca, Chile; [Gomez-Campos, Rossana] Univ Catolica Maule, Dept Divers & Inclus Classroom, Talca, Chile; [Correia de Campos, Luis Felipe Castelli] Univ Bio Bio, Dept Educ Sci, Chillan, Chile; [Sulla-Torres, Jose] Univ Natl San Agustin Arequipa, Arequipa, Peru; [Urra-Albornoz, Camilo] Univ Santo Tomas, Sch Kinesiol, Sch Hlth, Talca, Chile; [Lopes, Vitor Pires] Polytech Inst Braganca, Sport Sci Dept, Res Ctr Sports Sci Hlth Sci & Human Dev CIDESD, Braganca, Portugal in 2020, Cited 25. Quality Control of 5-Norbornene-2-carbonitrile. The Name is 5-Norbornene-2-carbonitrile. Through research, I have a further understanding and discovery of 95-11-4

Objective. To analyze the association between relative handgrip strength (RHGS) and fat mass (FM) after controlling for the potential effect of maturity status. Methodology. Both male and female children and adolescents aged >= 7.5 to <= 15.49 years were studied. RHGS was assessed using a hydraulic hand dynamometer. FM percentage was established using a dual-energy X-ray absorptiometry. Age and sex differences in RHGS levels between normal weight and obese participants were studied with an analysis of covariance. A covariate was years from peak height velocity (maturity status). The association between RHGS and FM levels was analyzed using a partial correlation and controlling for age at peak height velocity. Results. A total of 1685 students (731 girls and 954 boys) participated. Four age groups were established (7.5-9.4 years, 9.5-11.4 years, 11.5-13.4 years, and 13.5-15.4 years). RHGS increased with age in both males and females. FM values were high in all age groups. No differences were observed in groups 3 and 4 among girls or in group 4 among boys. Participants classified as normal weight showed a significantly higher RHGS than their obese peers. A negative association was noted between RHGS and FM. Conclusion. RHGS was shown to be negatively associated with FM after controlling for the effect of maturity status. About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Cossio-Bolanos, M; Gomez-Campos, R; de Campos, LFCC; Sulla-Torres, J; Urra-Albornoz, C; Lopes, VP or concate me.. Quality Control of 5-Norbornene-2-carbonitrile

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
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I found the field of Toxicology very interesting. Saw the article Development of a defined approach for eye irritation or serious eye damage for liquids, neat and in dilution, based on cosmetics Europe analysis of in vitro STE and BCOP test methods published in 2019. Category: nitriles-buliding-blocks, Reprint Addresses Adriaens, E (corresponding author), Adriaens Consulting BVBA, Bellemdorpweg 95, B-9881 Aalter, Belgium.. The CAS is 95-11-4. Through research, I have a further understanding and discovery of 5-Norbornene-2-carbonitrile

The focus of Cosmetics Europe’s programme on serious eye damage/eye irritation is on development of testing strategies and defined approaches for identification of ocular effects of chemicals in the context of OECD’s Guidance Document on an Integrated Approach on Testing and Assessment (IATA) for Serious Eye Damage and Eye Irritation. Cosmetics Europe created a comprehensive database of chemicals for which in vitro data are available with corresponding historical in vivo Draize eye data. This database allowed further exploration of the initially proposed strategies from the CON4EI project and to identify opportunities for refinement. The current analysis focused on the development of a defined approach, applicable to liquid non-surfactant chemicals, neat and in dilution, that can distinguish between the three UN GHS categories (Cat. 1, Cat. 2, and No Cat.). Combining the modified-protocol Short Time Exposure (STE) test method (OECD TG 491 with extension to highly volatile substances) with the Bovine Corneal Opacity and Permeability Laser Light-Based Opacitometer (BCOP LLBO) test method in a Bottom-Up approach identified 81.2% Cat. 1, 56.3% Cat. 2, and 85.3% No. Cat correctly, with an NPV of 96.7% and a PPV of 68.6%. Therefore, the performance of the defined approach was better than the standalone test methods.

About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Alepee, N; Adriaens, E; Abo, T; Bagley, D; Desprez, B; Hibatallah, J; Mewes, K; Pfannenbecker, U; Sala, A; Van Rompay, AR; Verstraelen, S; McNamee, P or concate me.. Category: nitriles-buliding-blocks

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
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HPLC of Formula: C8H9N. I found the field of Computer Science; Medical Informatics; Nursing very interesting. Saw the article Comparative Cost of Virtual Reality Training and Live Exercises for Training Hospital Workers for Evacuation published in 2019, Reprint Addresses Farra, SL (corresponding author), Wright State Univ, Coll Nursing & Hlth, 3640 Colonel Glenn Hwy, Dayton, OH 45435 USA.. The CAS is 95-11-4. Through research, I have a further understanding and discovery of 5-Norbornene-2-carbonitrile.

Adoption of virtual reality technology may be delayed due to high up-front costs with unknown returns on that investment. In this article, we present a cost analysis of using virtual reality as a training tool. Virtual reality was used to train neonatal intensive care workers in hospital evacuation. A live disaster exercise with mannequins was also conducted that approximated the virtual experience. Comparative costs are presented for the planning, development, and implementation of both interventions. Initially, virtual reality is more expensive, with a cost of $229.79 per participant (total cost $18 617.54 per exercise) for the live drill versus $327.78 (total cost $106 951.14) for virtual reality. When development costs are extrapolated to repeated training over 3 years, however, the virtual exercise becomes less expensive with a cost of $115.43 per participant, while the cost of live exercises remains fixed. The larger initial investment in virtual reality can be spread across a large number of trainees and a longer time period with little additional cost, while each live drill requires additional costs that scale with the number of participants.

About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Farra, SL; Gneuhs, M; Hodgson, E; Kawosa, B; Miller, ET; Simon, A; Timm, N; Hausfeld, J or concate me.. HPLC of Formula: C8H9N

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
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An article Biomolecule-derived supported cobalt nanoparticles for hydrogenation of industrial olefins, natural oils and more in water WOS:000486309300025 published article about LIQUID-PHASE HYDROGENATION; HIGHLY-ACTIVE HYDROGENATION; ORGANIC FRAMEWORK NODES; ASYMMETRIC HYDROGENATION; SELECTIVE HYDROGENATION; CATALYTIC-HYDROGENATION; COMPLEXES; ISOOCTENES; KINETICS; CO in [Pews-Davtyan, Anahit; Scharnagl, Florian Korbinian; Hertrich, Maximilian Franz; Kreyenschulte, Carsten; Bartling, Stephan; Lund, Henrik; Jackstell, Ralf; Beller, Matthias] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany in 2019, Cited 62. Name: 5-Norbornene-2-carbonitrile. The Name is 5-Norbornene-2-carbonitrile. Through research, I have a further understanding and discovery of 95-11-4

Catalytic hydrogenation of olefins using noble metal catalysts or pyrophoric RANEY (R) nickel is of high importance in the chemical industry. From the point of view of green and sustainable chemistry, design and development of Earth-abundant, less toxic, and more environmentally friendly catalysts are highly desirable. Herein, we report the convenient preparation of active cobalt catalysts and their application in hydrogenations of a wide range of terminal and internal carbon-carbon double bonds in water under mild conditions. Catalysts are prepared on multi-gram scale by pyrolysis of cobalt acetate and uracil, guanine, adenine or l-tryptophan. The most active material Co-Ura/C-600 showed good productivity in industrially relevant hydrogenation of diisobutene to isooctane and in natural oil hardening.

Name: 5-Norbornene-2-carbonitrile. About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Pews-Davtyan, A; Scharnagl, FK; Hertrich, MF; Kreyenschulte, C; Bartling, S; Lund, H; Jackstell, R; Beller, M or concate me.

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
Nitrile – Wikipedia,
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An article Modular Dual-Tasked C-H Methylation via the Catellani Strategy WOS:000490358900033 published article about PALLADIUM-CATALYZED ALKYLATION; LATE-STAGE FUNCTIONALIZATION; AROMATIC FUNCTIONALIZATION; SELECTIVE ALKYLATION; COUPLING REACTIONS; ARYL IODIDES; REAGENTS; BONDS; ACTIVATION; NORBORNENE in [Gao, Qianwen; Shang, Yong; Song, Fuzhen; Ye, Jinxiang; Liu, Ze-Shui; Li, Lisha; Cheng, Hong-Gang; Zhou, Qianghui] Wuhan Univ, Engn Res Ctr Organosilicon Cpds & Mat, Sauvage Ctr Mol Sci, Coll Chem & Mol Sci,Minist Educ, Wuhan 430072, Peoples R China; [Zhou, Qianghui] Wuhan Univ, Inst Adv Studies, Wuhan 430072, Peoples R China in 2019, Cited 91. Name: 5-Norbornene-2-carbonitrile. The Name is 5-Norbornene-2-carbonitrile. Through research, I have a further understanding and discovery of 95-11-4

We report a dual-tasked methylation that is based on cooperative palladium/norbornene catalysis. Readily available (hetero)aryl halides (39 iodides and 4 bromides) and inexpensive MeOTs or trimethylphosphate are utilized as the substrates and methylating reagent, respectively. Six types of ipso terminations can modularly couple with this ortho C-H methylation to constitute a versatile methylation toolbox for preparing diversified methylated arenes. This toolbox features inexpensive methyl sources, excellent functional-group tolerance, simple reaction procedures, and scalability. Importantly, it can be uneventfully extended to isotope-labeled methylation by switching to the corresponding reagents CD3OTs or (CH3OTs)-C-13. Moreover, this toolbox can be applied to late-stage modification of biorelevant substrates with complete stereoretention. We believe these salient and practical features of our dual-tasked methylation toolbox will be welcomed by academic and industrial researchers.

Name: 5-Norbornene-2-carbonitrile. About 5-Norbornene-2-carbonitrile, If you have any questions, you can contact Gao, QW; Shang, Y; Song, FZ; Ye, JX; Liu, ZS; Li, LS; Cheng, HG; Zhou, QH or concate me.

Reference:
Patent; Mitsui Chemicals, Inc.; KUMA, Shigetoshi; SAKATA, Michiharu; TOKUNAGA, Kouichi; SHIMAKAWA, Chitoshi; KAKINUMA, Naoyuki; FURUYA, Masayuki; TANAKA, Mamoru; EP2708527; (2014); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts