Tag: M.W=300-400

Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Article, Chemistry – An Asian Journal called Molybdenum Carbide-Embedded Multichannel Hollow Carbon Nanofibers as Bifunctional Catalysts for Water Splitting, Author is Ji, Changchun; Yang, Guang; Ilango, P. Robert; Song, Junnan; Yu, Deshuang; Han, Sujun; Zhang, Dongxing; Li, Linlin; Peng, Shengjie, which mentions a compound: 17524-05-9, SMILESS is O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O, Molecular C10H14MoO6, Computed Properties of C10H14MoO6.

With the environmental pollution and non-renewable fossil fuels, it is imperative to develop eco-friendly, renewable, and highly efficient electrocatalysts for sustainable energy. Herein, a simple electrospinning process used to synthesis Mo2C-embedded multichannel hollow carbon nanofibers (Mo2C-MCNFs) and followed by the pyrolysis process. As prepared lotus root-like nanoarchitecture could offer rich porosity and facilitate the electrolyte infiltration, the Mo2C-MCNFs delivered favorable catalytic activity for HER and OER. The resultant catalysts exhibit low overpotentials of 114 mV and 320 mV at a c.d. of 10 mA cm-2 for HER and OER, resp. Furthermore, using the Mo2C-MCNFs catalysts as a bifunctional electrode toward overall water splitting, which only needs a small cell voltage of 1.68 V to afford a c.d. of 10 mA cm-2 in the home-made alk. electrolyzer. This interesting work presents a simple and effective strategy to further fabricating tunable nanostructures for energy-related applications.

Here is a brief introduction to this compound(17524-05-9)Computed Properties of C10H14MoO6, if you want to know about other compounds related to this compound(17524-05-9), you can read my other articles.

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Asha, T. M.; Sithambaresan, M.; Prathapachandra Kurup, M. R. published an article about the compound: Bis(acetylacetonato)dioxomolybdenum(VI)( cas:17524-05-9,SMILESS:O=[Mo+2]12(O=C([CH-]C(C)=O1)C)(O=C([CH-]C(C)=O2)C)=O ).Electric Literature of C10H14MoO6. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:17524-05-9) through the article.

Four new mononuclear dioxidomolybdenum(VI) complexes [MoO2LD] (D = methanol (1), ethanol (2), propanol (3) and [MoO2LD]2·D (D = 4-picoline (4))) were synthesized by the reaction of [MoO2(acac)2] with the thiosemicarbazone (H2L) derived from 3-ethoxy-2-hydroxybenzaldehyde and N4-(3-methoxyphenyl)thiosemicarbazone in presence of donor solvents like methanol, ethanol, propanol and 4-picoline. Crystal and mol. structures of the complexes were determined by single crystal x-ray diffraction anal. All the complexes portrayed similar mononuclear structures where the thiosemicarbazone is bonded to molybdenum(VI) ion as a bineg. tridendate agent. The molybdenum(VI) center in complexes 1-4 is six coordinate by the thiosemicarbazone, two oxido groups and an oxygen or nitrogen atom from the donor solvent mols. The complexes 1-4 exhibit oxygen atom transfer to PPh3 in acetonitrile medium in presence of N-N bidendate donors to form [Mo(IV)OL(N-N)] (N-N = 2-2′ bipyridine (5) or 1,10 phenanthroline (6)). The complexes were further characterized by elemental anal., spectroscopic methods (IR, UV-visible and 1H NMR) and TGA. The electrochem. behavior of these complexes were investigated for an insight into the redox behavior of the molybdenum(VI) centers in these complexes. Hirshfeld surface anal. was successfully employed for exploring the coordination geometries and various noncovalent interactions present in their crystal structures. Also, the catalytic abilities of 1-4 were tested for the oxidation of styrene using aqueous H2O2 as oxidant and NaHCO3 as co-catalyst. The reaction condition for all-out catalytic proficiency of the catalysts 1-4 were examined by studying the effect of various parameters such as the amount of catalyst, H2O2, co-catalyst (NaHCO3) and solvent (CH3CN) as well as temperature of the reaction. Almost 97-98% product selectivity was attained for the oxidation of styrene to styrene oxide.

If you want to learn more about this compound(Bis(acetylacetonato)dioxomolybdenum(VI))Electric Literature of C10H14MoO6, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(17524-05-9).

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Related Products of 17524-05-9. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Bis(acetylacetonato)dioxomolybdenum(VI), is researched, Molecular C10H14MoO6, CAS is 17524-05-9, about Stable Bimetallene Hydride Boosts Anodic CO Tolerance of Fuel Cells. Author is Wu, Jiandong; Cui, Xiaoqiang; Fan, Jinchang; Zhao, Jingxiang; Zhang, Qinghua; Jia, Guangri; Wu, Qiong; Zhang, Dantong; Hou, Changmin; Xu, Shan; Jiao, Dongxu; Gu, Lin; Singh, David J.; Zheng, Weitao.

Active and durable anode electrocatalysts are of vital importance for practical implementation of fuel cells. However, the surface-adsorbed reaction intermediates, especially CO, easily poison and deactivate the electrocatalysts. Here, we report ultrathin molybdenum-palladium hydride (MoPdH) bimetallene as a high-efficiency electrocatalyst for the methanol oxidation reaction. This exhibits a 6.0-fold enhancement of mass activity relative to com. Pd black catalyst. Alloying with Mo strongly enhances the H binding ability of Pd and thereby stabilizes the MoPdH bimetallene. The resulting ultrathin hydride structure and the stabilization of it by Mo alloying yields a MoPdH bimetallene with the outstanding CO tolerance. The stabilization is understood in terms of the Miedema rule, which thus provides a new opportunity for catalyst design boosting the commercialization of fuel cells based on stable bimetallene hydride nanosheets.

Here is a brief introduction to this compound(17524-05-9)Related Products of 17524-05-9, if you want to know about other compounds related to this compound(17524-05-9), you can read my other articles.

Reference:
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Related Products of 103146-25-4,Some common heterocyclic compound, 103146-25-4, name is 4-(4-(Dimethylamino)-1-(4-fluorophenyl)-1-hydroxybutyl)-3-(hydroxymethyl)benzonitrile, molecular formula is C20H23FN2O2, traditional synthetic route has been very mature, but the traditional synthetic route has various shortcomings, such as complicated route, low yield, poor purity, etc, below Introduce a new synthetic route.

To a stirred solution [OF RACEMIC 4- [4-DIMETHYLAMINO-1- (4-FLUORO-PHENYL)-1-HYDROXY-] [BUTYL]-3-HYDROXYMETHYL-BENZONITRILE] (0,29 mmol, 100 mg) and vinylbutyrate (0,29 mmol, [37 L)] in anhydrous toluene (2,925 ml) is added Novozymes 435, (0,2 mg) and 1,1 eq. Carboxylic acid. The reaction is heated to 40 degrees celcius and followed by HPLC. The enzyme is filtered off and washed with a small amount of toluene. The combined organic phases are evaporated in vacuo and subsequently analyzed on super critical fluid chromatography. Result is shown in table 19.

These compound has a wide range of applications. It is believed that with the continuous development of the source of the synthetic route 4-(4-(Dimethylamino)-1-(4-fluorophenyl)-1-hydroxybutyl)-3-(hydroxymethyl)benzonitrile, its application will become more common.

Reference:
Patent; H. LUNDBECK A/S; WO2004/14821; (2004); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Researchers who often do experiments know that organic synthesis is a process of preparing more complex target molecules from simple raw materials through one or more chemical reactions. Generally, it requires fewer steps, and cheap raw materials. 103146-25-4, name is 4-(4-(Dimethylamino)-1-(4-fluorophenyl)-1-hydroxybutyl)-3-(hydroxymethyl)benzonitrile, A new synthetic method of this compound is introduced below., category: nitriles-buliding-blocks

Experiment 38. A range of experiments were conducted examining the resolution of diol with (+)- (S,S)-DTT. The general procedure is described below, and the details and results for each reaction are in table 1.Racemic diol (20 g, 58.4 mmol) was dissolved in approximately half of the solvent used for the experiment at 40 0C. (-H)-(S5S)-DTT-H2O (quantity specified in the table) was added as a solution in the other half of the solvent. The solution was held at 40 0C and was seeded within two minutes with crystals of (S)-diol. ./2(-H)-(S5S)-DTT (approximately 5 mg). Crystallisation typically began within 5-10 minutes after seeding. After 2 h at 40 0C, the temperature of the solution was lowered to 20 0C over 2 h, and the solution was held at this temperature for a further 1 h. The product was then separated by filtration, washed with the approriate solvent (2 x 20 mL) and dried overnight at 60 0C under reduced pressure.

The basis of chemical reaction formula synthesis, the synthesis route is composed of some specific reactions and combined according to certain logical thinking. We look forward to the emergence of more reaction modes in the future.

Reference:
Patent; H. LUNDBECK A/S; WO2009/33488; (2009); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Related Products of 103146-25-4, In the next few decades, the world population will flourish. As the population grows rapidly and people all over the world use more and more resources, all industries must consider their environmental impact. 103146-25-4, name is 4-(4-(Dimethylamino)-1-(4-fluorophenyl)-1-hydroxybutyl)-3-(hydroxymethyl)benzonitrile belongs to nitriles-buliding-blocks compound, it is a common compound, a new synthetic route is introduced below.

A test tube equipped with a stopper was charged with 10 mg (0.029 m mol) of [(=T :)-4-] [4-dimethylamino-1- (4′-fluorophenyl)-1-hydroxybutyl]-3-hydroxymethylbenzonitrile, 10 mg of Novozym 435 (product of NOvozymes), 33 mg (0.29 [M MOL)] of vinyl butyrate and 1 ml of various kinds of solvents, and stirred at [30C] for 16 hours. After the reaction, converted ratios and optical purities were analyzed and E-values were calculated. The results are shown in Table 9.

In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles, 4-(4-(Dimethylamino)-1-(4-fluorophenyl)-1-hydroxybutyl)-3-(hydroxymethyl)benzonitrile, other downstream synthetic routes, hurry up and to see.

Reference:
Patent; H. LUNDBECK A/S; WO2004/14821; (2004); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

In the chemical reaction process, reaction time, type of solvent, can easily affect the result of the reaction, thereby determining the yield and properties of the reaction product. An updated downstream synthesis route of 103146-25-4 as follows. SDS of cas: 103146-25-4

In a 200-ml four-necked flask equipped with a stirrer and a thermometer, 1.5 g [(4.] [38] m mol) of [()-4- [4-DIMETHYLAMINO-1- (4′-FLUOROPHENYL)-1-HYDROXYBUTYL]-3-] hydroxymethylbenzonitrile was dissolved in 30 ml of toluene, then 0.45 g of Novozym 435 (product [OF NOVOZYMES),] 0.347 g (4.38 m mol) of pyridine, 4.38 m mol of various kinds of acids and 1.00 g (8.76 m mol) of vinyl butyrate were added, and stirred at [40C] for between 16 and 21.5 hours. The result is shown in Table 4.

According to the analysis of related databases, 103146-25-4, the application of this compound in the production field has become more and more popular.

Reference:
Patent; H. LUNDBECK A/S; WO2004/14821; (2004); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Researchers who often do experiments know that organic synthesis is a process of preparing more complex target molecules from simple raw materials through one or more chemical reactions. Generally, it requires fewer steps, and cheap raw materials. 103146-25-4, name is 4-(4-(Dimethylamino)-1-(4-fluorophenyl)-1-hydroxybutyl)-3-(hydroxymethyl)benzonitrile, A new synthetic method of this compound is introduced below., HPLC of Formula: C20H23FN2O2

Experiment 36: Experiment 11 was repeated except that a mixture of 1-propanol and ethylacetate (31:69) was used as the solvent in stead of 1-propanol in a total volume of 4.5 V whereupon extra 2 V 1-propanol was added, 0.25 eq of (+)-O,O’-di-/?-toluoyl-(S,S)- tartaric acid was used, and the holding time before filtration was 0.5 h. Molar yield: 28.6%, enantiomeric purity: 98.4% S.

The synthetic route of 103146-25-4 has been constantly updated, and we look forward to future research findings.

Reference:
Patent; H. LUNDBECK A/S; WO2009/33488; (2009); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Synthetic Route of 103146-25-4, These common heterocyclic compound, 103146-25-4, name is 4-(4-(Dimethylamino)-1-(4-fluorophenyl)-1-hydroxybutyl)-3-(hydroxymethyl)benzonitrile, its traditional synthetic route has been very mature, but the traditional synthetic route has various shortcomings, such as complicated route, low yield, poor purity, etc, below Introduce a new synthetic route.

A test tube equipped with a stopper was charged with 10 mg (0.029 m mol) of [(=T :)-4-] [4-dimethylamino-1- (4′-fluorophenyl)-1-hydroxybutyl]-3-hydroxymethylbenzonitrile, 10 mg of Novozym 435 (product of NOvozymes), 33 mg (0.29 [M MOL)] of vinyl butyrate and 1 ml of various kinds of solvents, and stirred at [30C] for 16 hours. After the reaction, converted ratios and optical purities were analyzed and E-values were calculated. The results are shown in Table 9.

The synthetic route of 103146-25-4 has been constantly updated, and we look forward to future research findings.

Reference:
Patent; H. LUNDBECK A/S; WO2004/14821; (2004); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts

Adding a certain compound to certain chemical reactions, such as: 103146-25-4, name is 4-(4-(Dimethylamino)-1-(4-fluorophenyl)-1-hydroxybutyl)-3-(hydroxymethyl)benzonitrile, belongs to nitriles-buliding-blocks compound, can increase the reaction rate and produce products with better performance than those obtained under traditional synthetic methods. Here is a downstream synthesis route of the compound 103146-25-4, SDS of cas: 103146-25-4

The hydrobromide salt of racemic 4-[4-(dimethylamino)-1-(4′-fluorophenyl)-1-hydroxy-butyl]-3-(hydroxymethyl)-benzonitrile (50 g) was placed into a round bottom flask. Ethyl acetate (125 mL) was added and the mixture was stirred at 25-35 C. Aqueous sodium carbonate solution (19 g in 125 mL water) was added and the mixture was stirred at about 25-35 C. for 20 minutes. The layers were separated. The aqueous layer was extracted with ethyl acetate (125 mL). The organic layers were combined and washed with water (125 mL) followed by 10% sodium chloride solution (125 mL). The organic layer was evaporated under reduced pressure. The obtained residue was mixed with isopropanol (250 mL) and the mixture was heated at 40-50 C. for 10 minutes. (-)-Di-p-toluoyltartaric acid (23.8 g) was added. The mixture was stirred at 40-50 C. for 5 hours. The formed solid was filtered and washed with isopropanol (40 mL). The filtrate was evaporated under reduced pressure. The residue was mixed with ethyl acetate (125 mL). Aqueous sodium carbonate solution (12.3 g in 125 mL water) was added and the mixture was stirred at 25-35 C. for 20 minutes. The layers were separated and the aqueous layer was extracted with ethyl acetate (125 mL). The organic layers were combined and washed with water (125 mL) followed by 10% sodium chloride solution (125 mL). The solvent was evaporated under reduced pressure and the residue was mixed with a solvent mixture containing 3% by volume methanol in ethyl acetate (400 mL). (+) Di-p-toluoyltartaric acid (15 g) was added and the mixture was stirred at 25-35 C. for 3 hours. The mixture was heated to reflux, maintained at that temperature for 2 hours, and was cooled to 25-35 C. The solid was filtered, washed with a solvent mixture containing 3% methanol in ethyl acetate (50 mL) and dried at 50 C. Yield 83.8% of single enantiomer, chiral purity 98.35%.

In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles, 4-(4-(Dimethylamino)-1-(4-fluorophenyl)-1-hydroxybutyl)-3-(hydroxymethyl)benzonitrile, other downstream synthetic routes, hurry up and to see.

Reference:
Patent; Bolugoddu, Vijaya Bhaskar; Elati, Chandrasekhar Ravi Ram; Cheemalapati, Sasi Kala Venkata Annapurna; Penumandla, Rajagopal; Christy, Arulnathan Prabakar; Vakamudi, Lakshmi Vara Prasad Sree Naga Venkata; US2010/249438; (2010); A1;,
Nitrile – Wikipedia,
Nitriles – Chemistry LibreTexts